4-{[4-(Di­methyl­amino)­benzyl­idene]amino}­benzene­sulfonamide

نویسندگان

  • Mustafa Durgun
  • Hasan Türkmen
  • Tuncay Tunç
  • Tuncer Hökelek
چکیده

The title Schiff base compound, C15H17N3O2S, is non-planar with a dihedral angle of 69.88 (4)° between the planes of the benzene rings. In the crystal, pairs of N-H⋯N hydrogen bonds, between the sulfonamide nitro-gen-H atom and the azomethine N atom, link the mol-ecules into inversion dimers, forming R 2 (2)(16) ring motifs. These dimers are linked by N-H⋯O hydrogen bonds, between the sulfonamide nitro-gen-H atom and one sulfonamide O atom, forming sheets lying parallel to (100). Within the sheets there are weak parallel slipped π-π inter-actions involving inversion-related benzene-sulfonamide rings [centroid-centroid distance = 3.8800 (9) Å; normal distance = 3.4796 (6) Å; slippage = 1.717 Å].

برای دانلود متن کامل این مقاله و بیش از 32 میلیون مقاله دیگر ابتدا ثبت نام کنید

ثبت نام

اگر عضو سایت هستید لطفا وارد حساب کاربری خود شوید

منابع مشابه

(E)-4-Chloro-2-{[4-(di­methyl­amino)­benzyl­idene]amino}­phenol

In the title aromatic Schiff base compound, C15H15ClN2O, the mol-ecule exists in a trans conformation with respect to the C=N bond. The dihedral angle between the benzene rings is 14.49 (6)°. In the crystal, weak C-H⋯π inter-actions link mol-ecules into supra-molecular chains propagated along the a-axis direction.

متن کامل

N-[4-(Di­methyl­amino)­benzyl­idene]-4-methyl­aniline

The mol-ecules of the title compound, C16H18N2, exists in a trans conformation with respect to the C=N bond [1.270 (3) Å]. The least-squares plane of the di-methyl-amino group makes a dihedral angle of 1.3 (2)° with the ring to which it is attached. The dihedral angle between the two aromatic rings is 11.70 (2)°. The crystal structure features weak C-H⋯π inter-actions.

متن کامل

1-[4-(Di­methyl­amino)­benzyl­idene]-4-o-tolyl­thio­semicarbazide. Corrigendum

The correspondence address in the paper by Huang et al. [Acta Cryst. (2013), E69, o906-o907] is corrected.[This corrects the article DOI: 10.1107/S1600536813012890.].

متن کامل

(E)-N′-[4-(Di­methyl­amino)­benzyl­idene]-2-(4-methyl­phen­oxy)acetohydrazide

In the title compound, C18H21N3O2, the dihedral angle between the benzene rings is 68.85 (11)°. In the crystal, the mol-ecules are linked by C-H⋯O and N-H⋯O hydrogen bonds, as well as weak C-H⋯π contacts, forming a three-dimensional supra-molecular architecture.

متن کامل

5-Chloro-5′′-[4-(di­methyl­amino)­benzyl­idene]-4′-[4-(di­methyl­amino)­phen­yl]-1′,1′′-di­methyl­dispiro­[indoline-3,2′-pyrrolidine-3′,3′′-piperidine]-2,4′′-dione

The title compound, C34H38ClN5O2, has spiro links connecting the pyrrolidine ring and indole residue, as well as the piperidine and pyrrolidine rings. A half-chair conformation is found for the piperidine ring with the C atom connected to the spiro-C atom lying 0.738 (4) Å out of the plane of the remaining five atoms (r.m.s. deviation = 0.0407 Å). The methyl-ene C atom is the flap in the envelo...

متن کامل

ذخیره در منابع من


  با ذخیره ی این منبع در منابع من، دسترسی به آن را برای استفاده های بعدی آسان تر کنید

برای دانلود متن کامل این مقاله و بیش از 32 میلیون مقاله دیگر ابتدا ثبت نام کنید

ثبت نام

اگر عضو سایت هستید لطفا وارد حساب کاربری خود شوید

عنوان ژورنال:

دوره 70  شماره 

صفحات  -

تاریخ انتشار 2014